The power of accurately putting your opponent on a hand

Every once in awhile, you can put your opponent on exactly 2 cards.  If you can do that, you're playing a game with complete information where your opponent does not generally have the same information.  You have a huge advantage, because your opponent is playing his cards face up.  When you are in this position, take a gamble - you may pay incorrect pot odds, but your implied odds are HUGE.

Example:

This guy was a 14/4 over 473 hands with a 6% steal, with a very very low aggression factor.  He's got a legitimate hand...

Full Tilt Poker $0.25/$0.50 No Limit Hold'em - 9 players - http://www.thehandconverter.com/hands/662508
The Official DeucesCracked.com Hand History Converter

UTG: $47.25
UTG+1: $172.85
UTG+2: $19.65
MP1: $51.35
MP2: $35.05
CO: $65.50
BTN: $44.40
Hero (SB): $63.75
BB: $50.00

Pre Flop: ($0.75) Hero is SB with 2d 3d
6 folds, BTN calls $0.50, Hero calls $0.25, BB checks
Limped button?  32s is folding here under any raised circumstances, but I'll see a 1/2 price flop...

Flop: ($1.50) Qc 7s 4c (3 players)
Hero bets $1.50, BB folds, BTN calls $1.50
I cbet here with the expectation that he will fold everything in his range but hands that match the board.  Either he has a solid club draw, sets or AQ.  I don't think this type of player is floating at all.  He has a clearly defined range - with all but AA & KK limping.

At this point, I realize that my flop lead is dead in the water; I plan to check / fold just about everything.  I am clearly beat.

Turn: ($4.50) 5h (2 players)
Hero checks, BTN bets $2.50, Hero calls $2.50
What was I saying about check / folding?  I know what this guy has.  There's $40 remaining, and I'm now open-ended.

Talk about a nice card.  I can continue with the hand, and represent that I'm drawing to clubs.  At this point, I'm pretty certain that he has AQ and is protecting his TPTK.  I hope for a non-club A or 6 with the sole reason being that if a club pops on the river, he will be scared and fold.

River: ($9.50) Ad (2 players)
Hero bets $59.25 all in, BTN calls $39.90 all in
This is the *PERFECT CARD*!!!!  I know that if he has AQ, he's not folding any hand.  Given his aggression factor, if I pot bet, he's going to call.  I don't envision him ever raising.  How do I get paid?  Either he's got what I think he does or he doesn't.  Whatever I bet he's calling.  Shove seems to be the most viable action.  It works!  Note the overbet for value line; $10 pot and I push $60.

Final Pot: $89.30
BTN mucks Qs As
Hero shows 2d 3d (a straight, Five high)
Hero wins $86.30
(Rake: $3.00)